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Real-time measurement of molecular orientation using linear polarized light

In the optical waveguide spectroscopy, linearly polarized light can be used as the incident light. The longitudinal wave is used for P (TM) polarized light and the transverse wave for S (TE) polarized light, and the spectra are measured. And then the molecular orientation can be known from the absorption intensity ratio of each spectrum. (Fig.8,9,10)


Fig8. P(TM) polarization and S(TE) polarization

Fig9. Real-time measurement of methylene blue aggregation and orientation change due to TM polarization and TE polarization Quoted form K.Fujita,et al., Talanta,65,1066(2005).

Fig10. Image of aggregation and orientation process of methylene blue molecules Quoted from K.Fujita, et al., Talanta,65,1066(2005).

27. “Dynamic analysis of aggregation of methylene blue with polarized optical waveguide spectroscopy” Kyoko Fujita, Keisuke Taniguchi, Hiroyuki Ohno, Talanta, 65, 1066 (2005).

28. “Molecular orientation of azobenzene chromophores in ultrathin polymer nanosheets studied by attenuated total reflection spectroscopy” Masaya Mitsuishi, Tomohiro Tanuma, Jun Matsui, Tokuji Miyashita, Talanta, 65, 1091 (2005).

29. “Clay minerals as fascinating host materials for constructing nano-structure controlled systems” Shinsuke Takagi, Miharu Eguchi, Haruo Inoue, International Symposium on Physics and Chemistry of Smectites, 5 (2005).

30. “The orientational control of porphyrin molecule absorbed on inorganic nano-sheet” Miharu Eguchi, Shinsuke Takagi, Haruo Inoue, International Symposium on Physics and Chemistry of Smectites, 72 (2005).

31. “The Orientation Control of Dicationic Porphyrins on Clay Surfaces by Solvent Polarity” Miharu Eguchi, Shinsuke Takagi, and Haruo Inoue, Chem. Lett., 35, 1, 14 (2006).

32. “Solvatochromism of a membrane composed of a cationic porphyrin-clay complex” Shinsuke Takagi, Miharu Eguchi, D.A.Tryk, Haruo Inoue, 111st IUPAC SYMPOSIUM ON PHOTOCHEMISTRY Abstracts, 285 (2006).

33. “Dynamic Behavior of Porphyrin Orientation on the Clay Surfaces” Miharu Eguchi, Tetsuya Shimada, Hiroshi Tachibana, Donald Alexander Tryk, Shinsuke Takagi, and Haruo Inoue, 111st IUPAC SYMPOSIUM ON PHOTOCHEMISTRY Abstracts, 286 (2006).

34. “Dichroic Measurements on Dicationic and Tetracationic Porphyrins on Clay Surface with Visible-Light-Attenuated Total Reflectance” M. Eguchi, H. Tachibana, S. Takagi, Donald A. and H. Inoue, Bull. Chem. Soc. Jpn., 80, 7, 1350 (2007).

35. “Polarized optical waveguide spectroscopy: Effective tool to analyze adsorption process of dye molecules” Hiroyuki Ohno, Keisuke Taniguchi and Kyoko Fujita, Optical Review, 6, 3, 233 (2009).

36. “Molecular orientation of nonlinear optical polymer nanosheets on silica nanoparticle monolayer studied by optical waveguide spectroscopy” Miki Ishifuji, Takeo Suzuki, Masaya Mitsuishi and Tokuji Miyashita, Thin Solid Films, 518, 2, 457 (2009).

37. “Linearly Polarized Light Absorption Spectra of Chlorosomes, Light-Harvesting Antennas of Photosynthetic Green Sulfur Bacteria” Hitoshi Tamiaki, Shingo Tateishi, Shosuke Nakabayashi, Yutaka Shibata and Shigeru Itoh, Chem. Phys. Lett., 484, 4-6, 333 (2010).

38. “Observation of oriented molecular assemblies on ITO surfaces using porphyrin derivatives bearing carboxyl groups and their electrochemical responses” Katsuhiko Kanaizuka, Shigeta Yagyu, Hiromi Takahashi, Manabu Ishizaki, Masatomi Sakamoto,  Masato Kurihara, Electrochemistry, 80-7, 504 (2012).

39. “Role of Hydrophobic Interaction in Controlling the Orientation of Dicationic Porphyrins on Solid Surfaces” Miharu Eguchi, Tetuya Shimada, Donald A. TrykⅡ, Haruo Inoue, and Shinsuke Takagi, J. Phys. Chem. C, 117(18), 9245 (2013).

40. “Switching of energy transfer reaction by the control of orientation factor between porphyrin derivatives on the clay surface” Miharu Eguchi, Yo Watanabe, Yuta Ohtani, Tetuya Shimada, and Shinsuke Takagi, Tetrahedron Lett., 55, 2662 (2014).

41. “Patterning of Alkylamine Molecules on Highly Oriented Pyrolytic Graphite Surface via Deep UV Light Irradiation” Yusuke Sato, and Toshikazu Kawaguchi, Chem. Lett., 43, 10, 1542 (2014).